4018
Accession Number
22
Author
Dahl, Sverre; Kaplan, Arthur M.
Author Affiliation
National Bureau of Standards;Quartermaster Research and Engineering Command
Title Of Article Chaper
5, 6-dichloro-2-benzoxazolinone as a leather fungicide
Title Of Journal Book
The journal of the American Leather Chemists Association
Volume
52
Issue
12
Pages
686-698
Collation
13 p. : ill., 6 figs., 3 tables
Reference Bibliography
Includes bibliographical references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Meeting
The Seventh Biennial Conference of the International Union of Leather Chemists Societies
Meeting City
Washington, DC
Meeting Country
United States
Abstract
5,6-Dichloro-2-benzoxazolinone, a nonphenolic compound, has been investigated as a leather fungicide. Very mildew-susceptible leather, such as vegetable-tanned sole leather, is adequately mildew proofed by about 0. 4per thousand. A smaller percentage is adequate for other types of leather. The fungicide is stable, colorless, nonvolatile, and relatively resistant to removal by leaching with water. It is a much more effective leather fungicide than 2-benzoxazolinone, which indicates that the chlorine substituents are important. Because of the known general fungitoxic activity of phenols, it might be postulated that rupture of the oxazolinone ring with production of 2-amino-4,5-dichlorophenol occurs and that the latter compound constitutes the fungitoxic substance. However, this does not seem to occur in leather, as 5, 6-dichloro-2-benzoxazolinone is very stable under acid conditions. Furthermore, 2-amino-4, 5-dichlorophenol showed no fungitoxic activity when tested in leather.
Keywords
Skin leather, fungicide ICCROM
pub_id
4018
Meeting Date
19610820-19610825