2033
Accession Number
19829
Author
Chang, R.J.; Gent, A.N.
Title Of Article Chaper
Effect of interfacial bonding on the strength of adhesion of elastomers. Part 1. Self-adhesion
Title Of Journal Book
Journal of polymer science, polymer physics edition
Volume
19
Pages
1619-1633
Literature Type
Serial
Literature Level
Analytic
Abstract
Two partially gelled (crosslinked) layers of elastomer were pressed into intimate contact and the gelatin reaction was then taken to completion. By varying the extent of initial gelation, the degree of chemical interlinking was varied from zero, when two fully reacted sheets were pressed together, up to a level characteristic of the final density of molecular linking within each layer, when they were brought together before any reaction had occurred. The strength of adhesion between the layers was measured under threshold conditions, i.e., at low rates of peel, at high temperatures, and, in some instances, with the layers swollen with a compatible liquid. Linear relations were obtained between the threshold work of detachment per unit of interfacial area and the amount of chemical interlinking, deduced from the kinetics of molecularlinking within each layer. -- AATA
pub_id
2033