1809
Accession Number
30646
Author
Buchwald, Vagn Fabritius; Wivel, Helle
Author Affiliation
University of Denmark, Department of Metallurgy; University of Denmark, Department of Metallurgy
Title Of Article Chaper
Slag Analysis as a Method for the Characterization and Provenancing of Ancient Iron Objects
Title Of Journal Book
Materials Characterization
Volume
40
Pages
73-96
Collation
24 p. : ills.
Reference Bibliography
Includes bibliographic references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
About 900 slags and iron objects from the period 700 B.C. to 1850 A.D. have been examined and analyzed by classical optical microscopy and by energy dispersive analytical methods. Although ancient iron objects are extremely heterogeneous, a definite correlation between the metal phase and its slag inclusions is shown; for example, wustite-rich slags are located in ferrite, whereas glassy slags are located in pearlite. The ratios SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>O<sub>3</sub>/CaO, and so forth, of the slag inclusions are shown to be helpful in identifying the production site or provenance of an ancient iron object. These ratios are further shown not to be the same in irons produced by the direct process and in irons produced by fining or puddling. Emphasis is on iron production methods in Sweden, Norway, and Denmark, illuminating Scandinavian iron-making practices through 2500 years. The slag analysis method developed here may, however, be extended to yield information on other European sites.
Keywords
slag; analysis; method; characterization; provenance; iron; object; metallurgy
pub_id
1809