272
Editor
Vontobel, Roy
Title Of Article Chaper
Double the life for each five-degree drop, more than double the life for each halving of relative humidity
Title Of Journal Book
ICOM Committee for Conservation. 13<sup>th</sup> Trienniel Meeting, Rio de Janeiro, 22-27 September 2002. Preprints volume 1
Pages
66-72
Publisher
James & James (Science Publishers)
Publisher City
London
Language Of Text
English
Literature Type
Monograph
Literature Level
Analytic
Meeting
ICOM. 13<sup>th</sup> Triennial Meeting
Meeting City
Rio de Janeiro
Meeting Country
Brazil
Abstract
Data on accelerated ageing and the effect of temperature and relative humidity (RH) are reviewed for paper, film and magnetic media studies. The activation energy for most paper and film studies falls in the range (80 to 120) kJmol<sup>-1</sup>. For decay in magnetic media binder and yellowing of damar resin, the activation energies fall in a lower range, (60 to 80) kJ mol<sup>-1</sup>. The average activation energy value of 100 kJmol<sup>-1</sup> implies a rule of thumb: double the lifetime for each 5 C drop, so 70 kJmol<sup>-1</sup> implies 7 C. A theoretical derivation from transition state theory suggests that these approximate rules are predictable and, hence, universal for materials in museums with chemical instability problems. The available data on relative humidity dependence suggests that half the relative humidity will more than double lifetimes for acid hydrolysis. Hence, the title of this article holds generally for museums. A graph of constant lifetimes on the psychrometric chart is presented. -- CCI=IC
Keywords
Paper; Photographic film; Magnetic tape; Deterioration; Temperature; Relative humidity; Accelerated ageing; Test; Analysis -- ICCROM
pub_id
272
Meeting Date
20020922-20020927