181
Accession Number
14901
Author
Croll, S.G.
Title Of Article Chaper
The origin of residual internal stress in solvent-cast thermoplastic coatings
Title Of Journal Book
Journal of applied polymer science
Volume
23
Issue
3
Pages
847-858
Collation
12 p. : ills., 4 figs.
Reference Bibliography
Includes bibliographical references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
Experiments on polystyrene and poly(isobutyl methacrylate) coatings cast from toluene have shown that residual internal stress is independent of dried coating thickness and initial solution concentration. A theory is presented that predicts the magnitude of the stress and shows that it has no dependence of thickness or initial solution concentration. Internal strain is calculated from the volume of solvent lost after the coating has solidified. This solidification point is identified with the solvent concentration that is sufficient to depress the glass transition of the polymer to the prevailing experimental temperature. A one-to-one correlation is confirmed between the volume of solvent lost from solution during drying and the volume change of the polymer film.
pub_id
181